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A process for the preparation of a latex by for example, the polymerization of monomer in the presence of a catalytic chain transfer component, and an initiator.

Inventors: Chieh-Min Cheng, Dwight J. Tshudy
Original Assignee: Xerox Corporation
Current U.S. Classification: 430/137.12; 430/137.17; 523/335
International Classification: G03G 9087

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Citations

Cited PatentFiling dateIssue dateOriginal AssigneeTitle
US367473615 Jun 196610 Jun 1972PROCESS FOR THE PREPARATION OF PIGMENTED POLYMER POWDERS OF CONTROLLED PARTICLE SHAPE AND SIZE AND SIZE DISTRIBUTION AND PRODUCT
US41371881 Feb 197830 Jan 1979Magnetic toner for electrophotography
US45581089 Oct 198410 Dec 1985Xerox CorporationAqueous suspension polymerization process
US479733930 Oct 198610 Jan 1989Nippon Carbide Koyo Kabushiki KaishaToner for developing electrostatic images
US498348830 Mar 19908 Jan 1991Hitachi Chemical Co., Ltd.Process for producing toner for electrophotography
US499612723 Sep 198826 Feb 1991Nippon Carbide Kogyo Kabushiki KaishaToner for developing an electrostatically charged image
US50665607 Sep 199019 Nov 1991Hitachi Chemical Company, Ltd.Process for producing toner for electrophotography
US527802028 Aug 199211 Jan 1994Xerox CorporationToner composition and processes thereof
US529065429 Jul 19921 Mar 1994Xerox CorporationMicrosuspension processes for toner compositions
US530873414 Dec 19923 May 1994Xerox CorporationToner processes
US534473825 Jun 19936 Sep 1994Xerox CorporationProcess of making toner compositions
US534679725 Feb 199313 Sep 1994Xerox CorporationToner processes
US536472925 Jun 199315 Nov 1994Xerox CorporationToner aggregation processes
US537096325 Jun 19936 Dec 1994Xerox CorporationToner emulsion aggregation processes
US540369325 Jun 19934 Apr 1995Xerox CorporationToner aggregation and coalescence processes
US541810825 Jun 199323 May 1995Xerox CorporationToner emulsion aggregation process
US55610253 Jul 19951 Oct 1996Xerox CorporationToner aggregation processes

Referenced by

Citing PatentFiling dateIssue dateOriginal AssigneeTitle
US623919330 Aug 199929 May 2001Xerox CorporationInk compositions comprising a latex and processes thereof
US655932730 Apr 20016 May 2003E. I. du Pont de Nemours and CompanyAlkyl cobalt (III) dioximates and process for forming the same
US671342721 Feb 200330 Mar 2004E. I. du Pont de Nemours and CompanyAlkyl cobalt (III) dioximates and process for forming the same
US674061821 Feb 200325 May 2004E. I. du Pont de Nemours and CompanyAlkyl cobalt(III) dioximates and process for forming the same
US685874521 Feb 200322 Feb 2005E. I. du Pont de Nemours and CompanyAlkyl cobalt (III) dioximates and process for forming the same
US68727897 Nov 200229 Mar 2005Akzo Nobel N.V.Cross-linkable polymer composition
US746823227 Apr 200523 Dec 2008Xerox CorporationProcesses for forming latexes and toners, and latexes and toner formed thereby
US76783073 Nov 200616 Mar 2010Materials Innovation Technologies, LLCVortex control in slurry molding applications
US814297529 Jun 201027 Mar 2012Xerox CorporationMethod for controlling a toner preparation process
US81782695 Mar 201015 May 2012Xerox CorporationToner compositions and methods
US82219515 Mar 201017 Jul 2012Xerox CorporationToner compositions and methods

Claims

1. A process for the preparation of a latex comprising the polymerization of monomer in the presence of a catalytic chain transfer component, and an initiator.

2. A process in accordance with claim 1 wherein the catalytic chain transfer agent is a cobalt complex.

3. A process in accordance with claim 1 wherein the chain transfer component is cobalt(II) porphyrin, cobalt (II) dioxime, cobalt (III) dioxime, iridium (II) porphyrin, or rhoium (II) porphyrin.

4. A process in accordance with claim 2 wherein the catalytic chain transfer agent is Co(II)(2,3-dioxyiminobutane-BF.sub.2).sub.2.

5. A process in accordance with claim 1 wherein the chain transfer agent is selected in an amount of from about 0.001 to about 1 weight percent based on the amount of monomer selected for the preparation of the latex polymer.

6. A process in accordance with claim 1 wherein the chain transfer agent is selected in an amount of from about 0.01 to about 0.5 weight percent.

7. A process in accordance with claim 1 wherein the monomer is selected from the group consisting of alkyl acrylates, alkyl methacrylates, styrenes, acrylonitriles, dienes, vinyl esters, acid olefinic monomers, and basic olefinic monomers, wherein said alkyl contains from 1 to about 10 carbon atoms, alkyl acrylates of about C1 to about C10 carbon atoms; said styrenes are styrene, .alpha.-methyl styrene, and t-butyl styrene; said acrylonitriles are acrylonitrile or methacrylonitrile; said dienes are butadiene or isoprene; said vinyl esters are vinyl acetate or vinyl butyrate; said acid olefinic monomers are acrylic acid, methacrylic acid, fumaric acid, maleic acid, or itaconic acid; and said basic olefinic monomers are acrylamide, methacrylamide, vinylpyridine, vinylpyrrolidone, or vinyl-N-methacrylpyridinium.

8. A process in accordance with claim 1 wherein there is formed from the polymerization of monomer, polymers of poly(styrene-butadiene), poly(methyl methacrylate-butadiene), poly(ethyl methacrylate-butadiene), poly(propyl methacrylate-butadiene), poly(butyl methacrylate-butadiene), poly(methyl acrylate-butadiene), poly(ethyl acrylate-butadiene), poly(propyl acrylate-butadiene), poly(butyl acrylate-butadiene), poly(styrene-isoprene), poly(methylstyrene-isoprene), poly(methyl methacrylate-isoprene), poly(ethyl methacrylate-isoprene), poly(propyl methacrylate-isoprene), poly(butyl methacrylate-isoprene), poly(methyl acrylate-isoprene), poly(ethyl acrylate-isoprene), poly(propyl acrylate-isoprene), poly(butyl acrylate-isoprene), poly(styrene-butylacrylate), poly(styrene-butyl methacrylate), poly(styrene-butyl acrylate-acrylic acid), poly(styrene-butadiene-acrylic acid), poly(styrene-isoprene-acrylic acid), poly(styrene-butyl methacrylate-acrylic acid), poly(methyl methacrylate-butyl acrylate), poly(butyl methacrylate-butyl acrylate), poly(butyl methacrylate-acrylic acid), poly(styrene-butyl acrylate-acrylonitrile-acrylic acid), poly(methyl methacrylate-butyl acrylate-acrylic acid), or poly(acrylonitrile-butyl acrylate-acrylic acid).

9. A process in accordance with claim 1 wherein said monomer is selected in an amount of from about 40 to about 100 percent by weight, or from about 70 to about 100 percent of the monomers used to prepare the latex polymer.

10. A process in accordance with claim 1 wherein heating is selected to accomplish the polymerization of said monomer.

11. A process in accordance with claim 1 wherein heating is selected to accomplish the polymerization of said monomer and wherein said heating is at a temperature of from about 50 to about 95 degrees Centigrade, and wherein the latex contains substantially no sediment.

12. A process for the preparation of toner comprising

(i) aggregating a colorant dispersion with the polymer latex emulsion of claim 1;
(ii) coalescing and fusing the aggregates generated; and
(iii) isolating, washing, and drying the toner.

13. A process in accordance with claim 12 wherein said aggregating is below about the polymer glass transition temperature present in the latex emulsion, the coalescing and fusing of said aggregates is above about the latex polymer glass transition temperature, and there results toner with a size of from about 2 to about 20 microns in volume average diameter.

14. A process in accordance with claim 13 wherein said temperature below the glass transition temperature is from about 25.degree. C. to about 60.degree. C., and the heating above the glass transition temperature is from about 60.degree. C. to about 100.degree. C.

15. A process in accordance with claim 13 wherein said temperature below the glass transition temperature is from about 35.degree. C. to about 55.degree. C., and the heating above the glass transition temperature is from about 70.degree. C. to about 95.degree. C.

16. A process in accordance with claim 12 wherein the temperature at which said aggregation is accomplished controls the size of the aggregates, and wherein the final toner size is from about 2 to about 12 microns in average volume diameter, and wherein the temperature and time of said coalescence of the components of aggregates control the shape of the resultant toner.

17. A process in accordance with claim 13 wherein the aggregation temperature of is from about 45.degree. C. to about 55.degree. C., and wherein the coalescing temperature is from about 80.degree. C. to 95.degree. C.

18. A process in accordance with claim 12 wherein there is further selected a cosurfactant selected from the group consisting of components of alkanes, hydrocarbyl alcohols, ethers, amines, halides, and esters.

19. A process in accordance with claim 12 wherein the colorant is a pigment and wherein said pigment dispersion contains an ionic surfactant.

20. A process in accordance with claim 19 wherein the surfactant utilized in the colorant dispersion is a cationic surfactant.

21. A process in accordance with claim 12 wherein the aggregating is conducted at a temperature that about 15.degree. C. to about 1.degree. C. below the Tg of the polymer contained in the latex, for a duration of from about 0.5 hour to about 3 hours.

22. A process in accordance with claim 12 wherein the coalescing of the components of aggregates for the formation of integral toner particles comprised of colorant, and resin, or polymer is accomplished at a temperature of about 85.degree. C. to about 105.degree. C. for a duration of from about 1 hour to about 5 hours.

23. A process in accordance with claim 1 wherein a monomer is selected to enable a latex polymer and which monomer is selected from the group consisting of poly(styrene-alkyl acrylate), poly(styrene-1,3-diene), poly(styrene-alkyl methacrylate), poly(styrene-alkyl acrylate-acrylic acid), poly(styrene-1,3-diene-acrylic acid), poly(styrene-alkyl methacrylate-acrylic acid), poly(alkyl methacrylate-alkyl acrylate), poly(alkyl methacrylate-aryl acrylate), poly(aryl methacrylate-alkyl acrylate), poly(aryl methacrylate-alkyl acrylate-acrylic acid), poly(alkyl methacrylate-acrylic acid), poly(styrene-alkyl acrylate-acrylonitrile-acrylic acid), poly(styrene-1,3-diene-acrylonitrile-acrylic acid), and poly(alkyl acrylate-acrylonitrile-acrylic acid), and wherein said polymer is optionally present in an effective amount of from 80 percent by weight to about 98 percent by weight of toner.

24. A process in accordance with claim 12 wherein the toner particles isolated are from about 2 to about 10 microns in average volume diameter, and the particle size distribution thereof is from about 1.15 to about 1.30, and wherein there is added to the surface of the formed toner metal salts, metal salts of fatty acids, silicas, metal oxides, or mixtures thereof, each in an amount of from about 0.1 to about 10 weight percent of the obtained toner particles.

25. A process in accordance with claim 12 wherein there is selected for said latex preparation a cobalt complex catalytic chain transfer agent.

26. A process in accordance with claim 1 wherein said polymerization is accomplished in the presence of a nonionic surfactant.

27. A process in accordance with claim 1 wherein heating is selected to accomplish the polymerization of said monomer and wherein said heating is at a temperature of from about 25 to about 120 degrees Centigrade.