CA2294429A1 - Admixture and method for optimizing addition of eo/po superplasticizer to concrete containing smectite clay-containing aggregates - Google Patents
Admixture and method for optimizing addition of eo/po superplasticizer to concrete containing smectite clay-containing aggregates Download PDFInfo
- Publication number
- CA2294429A1 CA2294429A1 CA002294429A CA2294429A CA2294429A1 CA 2294429 A1 CA2294429 A1 CA 2294429A1 CA 002294429 A CA002294429 A CA 002294429A CA 2294429 A CA2294429 A CA 2294429A CA 2294429 A1 CA2294429 A1 CA 2294429A1
- Authority
- CA
- Canada
- Prior art keywords
- clay
- plasticizer
- agent
- water
- cation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004927 clay Substances 0.000 title abstract 14
- 229910021647 smectite Inorganic materials 0.000 title abstract 2
- 239000008030 superplasticizer Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 6
- 239000004014 plasticizer Substances 0.000 abstract 6
- 229920000642 polymer Polymers 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002892 organic cations Chemical class 0.000 abstract 2
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- 150000001412 amines Chemical group 0.000 abstract 1
- 150000001767 cationic compounds Chemical class 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000004568 cement Substances 0.000 abstract 1
- 229910001411 inorganic cation Inorganic materials 0.000 abstract 1
- 125000005702 oxyalkylene group Chemical group 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/40—Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
- C04B24/42—Organo-silicon compounds
- C04B24/425—Organo-modified inorganic compounds, e.g. organo-clays
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
- C04B14/104—Bentonite, e.g. montmorillonite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
- C04B14/106—Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
Abstract
In the preparation of aqueous cement compositions containing a plasticizer, such as an EO/PO polymer-containing plasticizer, or EO/PO comb polymer-containing plasticizer, and further containing clay, such as a smectite clay, which expands when in contact with water, the step of providing an agent operative to modify the clay whereby the plasticizer absorbing capability of the clay is reduced. In exemplary methods of the invention, the plasticizer is an EO/PO (e.g., oxyalkylene) plasticizer and preferably an EO/PO comb polymer, and the clay-activity-modifiying agent may comprise an inorganic cation, an organic cation, a polar organic molecule capable of being absorbed by the clay, a clay dispersant (such as a polyphosphate), or a mixture thereof. For clay-activity-modifying agents which comprise a cation or a polar organic molecule, the agent is preferably added to the clay before water is introduced to the clay. For clay dispersant agents and some organic cations such as quaternary amines (which have a strong affinity for cationic exchange with the clay), the agent may be added before, during, or after water is introduced to the clay.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5069797P | 1997-06-25 | 1997-06-25 | |
US60/050,697 | 1997-06-25 | ||
PCT/US1998/012876 WO1998058887A1 (en) | 1997-06-25 | 1998-06-19 | Admixture and method for optimizing addition of eo/po superplasticizer to concrete containing smectite clay-containing aggregates |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2294429A1 true CA2294429A1 (en) | 1998-12-30 |
CA2294429C CA2294429C (en) | 2003-12-09 |
Family
ID=21966840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002294429A Expired - Lifetime CA2294429C (en) | 1997-06-25 | 1998-06-19 | Admixture and method for optimizing addition of eo/po superplasticizer to concrete containing smectite clay-containing aggregates |
Country Status (15)
Country | Link |
---|---|
US (2) | US6352952B1 (en) |
EP (2) | EP1015398B1 (en) |
JP (1) | JP4491078B2 (en) |
KR (1) | KR100562920B1 (en) |
CN (2) | CN1098822C (en) |
AU (1) | AU731822B2 (en) |
BR (1) | BR9810323A (en) |
CA (1) | CA2294429C (en) |
DE (1) | DE69841672D1 (en) |
ES (1) | ES2344490T3 (en) |
NZ (1) | NZ502141A (en) |
RU (1) | RU2187479C2 (en) |
TR (1) | TR199903254T2 (en) |
TW (1) | TW387868B (en) |
WO (1) | WO1998058887A1 (en) |
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EP4215504A1 (en) | 2022-01-20 | 2023-07-26 | Sika Technology AG | Method for mitigating the effect of clay in mineral construction materials |
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- 1998-06-19 KR KR19997012337A patent/KR100562920B1/en not_active IP Right Cessation
- 1998-06-19 AU AU79825/98A patent/AU731822B2/en not_active Expired
- 1998-06-19 CA CA002294429A patent/CA2294429C/en not_active Expired - Lifetime
- 1998-06-19 DE DE69841672T patent/DE69841672D1/en not_active Expired - Lifetime
- 1998-06-19 BR BR9810323-7A patent/BR9810323A/en not_active IP Right Cessation
- 1998-06-19 EP EP98930431A patent/EP1015398B1/en not_active Expired - Lifetime
- 1998-06-19 WO PCT/US1998/012876 patent/WO1998058887A1/en not_active Application Discontinuation
- 1998-06-19 TR TR1999/03254T patent/TR199903254T2/en unknown
- 1998-06-19 NZ NZ502141A patent/NZ502141A/en unknown
- 1998-06-19 JP JP50489899A patent/JP4491078B2/en not_active Expired - Lifetime
- 1998-06-19 US US09/446,590 patent/US6352952B1/en not_active Expired - Lifetime
- 1998-06-19 CN CN98808461A patent/CN1098822C/en not_active Expired - Lifetime
- 1998-06-19 ES ES98930431T patent/ES2344490T3/en not_active Expired - Lifetime
- 1998-06-19 RU RU2000101841/04A patent/RU2187479C2/en not_active IP Right Cessation
- 1998-06-19 EP EP10003538A patent/EP2210865A1/en not_active Withdrawn
- 1998-06-19 CN CNB02150475XA patent/CN100400457C/en not_active Expired - Lifetime
- 1998-07-22 TW TW087111949A patent/TW387868B/en active
-
2001
- 2001-11-06 US US09/993,726 patent/US6670415B2/en not_active Expired - Lifetime
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US20020121229A1 (en) | 2002-09-05 |
CN1421413A (en) | 2003-06-04 |
US6352952B1 (en) | 2002-03-05 |
KR20010014236A (en) | 2001-02-26 |
BR9810323A (en) | 2000-09-05 |
JP2002506415A (en) | 2002-02-26 |
NZ502141A (en) | 2001-12-21 |
CA2294429C (en) | 2003-12-09 |
RU2187479C2 (en) | 2002-08-20 |
ES2344490T3 (en) | 2010-08-27 |
MX9911839A (en) | 2000-04-30 |
EP1015398A4 (en) | 2002-02-06 |
WO1998058887A1 (en) | 1998-12-30 |
CN1268101A (en) | 2000-09-27 |
AU731822B2 (en) | 2001-04-05 |
MX225224B (en) | 2005-01-03 |
KR100562920B1 (en) | 2006-03-22 |
CN100400457C (en) | 2008-07-09 |
CN1098822C (en) | 2003-01-15 |
DE69841672D1 (en) | 2010-07-01 |
TW387868B (en) | 2000-04-21 |
EP1015398B1 (en) | 2010-05-19 |
US6670415B2 (en) | 2003-12-30 |
EP2210865A1 (en) | 2010-07-28 |
EP1015398A1 (en) | 2000-07-05 |
TR199903254T2 (en) | 2000-07-21 |
AU7982598A (en) | 1999-01-04 |
JP4491078B2 (en) | 2010-06-30 |
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